Summary
Alongside alternative clean energy sources, energy recovery and conversion will play an important role in addressing future technologies, especially for autonomous devices. Thermoelectric devices convert temperature gradients into electric power and vice versa have been actively investigated to enhance existing technologies for heat/power recovery and conversion.
They are reliable, non-polluting, require minimal maintenance, and can be operated over a wide range of temperatures. If it were not for its currently low efficiency, thermoelectric energy conversion could revolutionary replace thermomechanical conversion in many applications. The performance of thermoelectric materials is expressed by the dimensionless figure-of-merit, zT, which is about 1.2 for materials currently used in thermoelectric devices. For wide adoption, the zT needs to reach a value of three, a goal that has been pursued for over 50 years. Recent record zT values approaching two are driven in part by nanocrystals self-precipitated in bulk, even though control and understanding of nanocrystal formation remain elusive in these systems.
UT-BORN-PT aimed at significantly increasing zT values of thermoelectrics by nanostructuring thermoelectric materials into nanocrystal solids that can offer high electrical conductivity while dramatically lowering the thermal conductivity. The project proposed an approach to creating completely new high-zT thermoelectrics via the bottom-up assembly of thermoelectric nanocrystals.
Thermoelectric generators (TEGs) interconverts heat and electrical energy, and are energy recovery and conversion devices with enormous potential to harvest the dissipated heat from power plants, automotive engines, housing heating systems, and even electronic devices for micro-power generation applications.
The synthesized BNSLs based thermoelectric materials have led to the development of next-generation of thermoelectrics and concurrently will provide a fundamental breakthrough for simple, scalable and low-cost processing of high-performance TEGs.
| Title | Unconventional Thermoelectrics Based on Self-Organized Binary Nanocrystal Superlatices |
| Reference | UTAP-EXPL/CTE/0050/2017 |
| Scientific Area | Nanotechnologies |
| Funding | € 98 881,00 plus matched funding at UT Austin |
| Leading Institution | Laboratório Ibérico Internacional de Nanotecnologias (INL) |
| Participating Institutions | The University of Austin at Texas (UT Austin) Universidade do Minho (UM) |
| Duration | 18 months |
| Begin date | November 1, 2018 |
| End date | April 30, 2020 |
| Keywords | Self-assembly, Nanocrystal superlatices, Nanostructured thermoelectrics, Transport properties |
Main Highlights
- Scalable thermochemical alloying route for synthesizing chalcogenides nanocrystals;
- Cumulative temperature dependence approach for estimation of realistic thermoelectric performance;
- Bulk nanostructured n-type alloys with ZTavg≈0.7 with an estimated thermoelectric conversion efficiency of approx. 5-6%;
- Bulk p-type nanocomposite with ZTavg≈1.2 for low-temperature thermoelectric application;
- Ligand engineered phase-pure 150 nm thick films of oleate-capped PbTe NCs with reduced thermal conductivity.
Indicators
- 5 Published papers in peer-reviewed Journals and Conferences;
- 2 Undergraduate students involved in research work;
- 1 Mobility exchange supported;
- 1 New funding application deriving from UT-BORN-PT (H2020).
Papers and Communications
- Piotrowski, M., Franco, M., Sousa, V., Rodrigues, J., Deepak, F. L., Kakefuda, Y., Kawamoto, N., Baba, T., Owens-Baird, B., Alpuim, P., Kovnir, K., Mori, T., & Kolen’ko, Y. V. (2018). Probing of Thermal Transport in 50 nm Thick PbTe Nanocrystal Films by Time-Domain Thermoreflectance. In The Journal of Physical Chemistry C (Vol. 122, Issue 48, pp. 27127–27134). American Chemical Society (ACS). https://doi.org/10.1021/acs.jpcc.8b04104
- Piotrowski, M., Borme, J., Carbó-Argibay, E., Sharma, D., Nicoara, N., Sadewasser, S., Petrovykh, D. Y., Rodríguez-Abreu, C., & Kolen’ko, Y. V. (2019). Template-directed self-organization of colloidal PbTe nanocrystals into pillars, conformal coatings, and self-supported membranes. In Nanoscale Advances (Vol. 1, Issue 8, pp. 3049–3055). Royal Society of Chemistry (RSC). https://doi.org/10.1039/c9na00370c
- Chauhan, N. S., Bathula, S., Gahtori, B., Kolen’ko, Y. V., Shyam, R., Upadhyay, N. K., & Dhar, A. (2019). Spinodal decomposition in (Ti, Zr)CoSb half-Heusler: A nanostructuring route toward high efficiency thermoelectric materials. In Journal of Applied Physics (Vol. 126, Issue 12, p. 125110). AIP Publishing. https://doi.org/10.1063/1.5109091
- Chauhan, N. S., Raghuvanshi, P. R., Tyagi, K., Johari, K. K., Tyagi, L., Gahtori, B., Bathula, S., Bhattacharya, A., Mahanti, S. D., Singh, V. N., Kolen’ko, Y. V., & Dhar, A. (2020). Defect Engineering for Enhancement of Thermoelectric Performance of (Zr, Hf)NiSn-Based n-type Half-Heusler Alloys. In The Journal of Physical Chemistry C (Vol. 124, Issue 16, pp. 8584–8593). American Chemical Society (ACS). https://doi.org/10.1021/acs.jpcc.0c00681
- Upadhyay, N. K., Chauhan, N. S., Kumaraswamidhas, L. A., Johari, K. K., Gahtori, B., Bathula, S., Reddy, R., Kolen’ko, Y. V., Dhakate, S. R., & Dhar, A. (2020). Facile bulk synthesis of high performance β-Zn4Sb3 for thermoelectric applications. In Materials Letters (Vol. 265, p. 127428). Elsevier BV. https://doi.org/10.1016/j.matlet.2020.127428
E-Poster
Project Team
Yury Kolen’ko
UT-BORN-PT
Brian Korgel
UT-BORN-PT
